Infrared investigations or the one-dimensionalorganic condcutors (perylene)2M(mnt)2, M=Au, Pt
Drichko, N. D.
;
Matos, M.
;
Henriques, R. T.
; Almeida, M.
European Physical Journal B Vol. 78, Nº 3, pp. 283 - 289, December, 2010.
ISSN (print): 1434-6028
ISSN (online): 1434-6036
Scimago Journal Ranking: 1,10 (in 2010)
Digital Object Identifier:
Abstract
The optical properties of the one-dimensional organic conductor (perylene)(2)Pt(mnt)(2) and its Au analogue have been investigated at ambient and low temperatures. The spectra along the stacks of the molecules show a simple Drude behavior with no detectable influence of electron-electron interactions. Basing on the spectra for different polarizations an assignment of the vibrational modes is made. Perpendicular to the stacks, a wide band observed in the mid-infrared range evidences a charge transfer between perylene and anion stacks. The electronic properties are discussed in comparison with other quasi-one-dimensional synthetic metals.
