A group of new tetracoordinate mononuclear 2-(N-phenylformimino)pyrrolyl boron chelates [BX2{κ2
N,N’-
NC4H3-2-C(H)vN-C6H5}] (X = F 3; mesityl (2,4,6-trimethylphenyl, Mes) 4; C6F5 5; X2 = 1,1’-biphenyl-2,2’-
diyl 6) and the related binuclear complex [(C6F5)2B{κ2
N,N’-NC4H3-2-C(H)vN-C6H4-NvC(H)-C4H3Nκ2
N,N’}B(C6F5)2] 7 were synthesised via metathetic exchange reactions of sodium 2-(N-phenylformimino)
pyrrolyl with BF3·Et2O (3), BMes2F (4) and 9-chloro-9-borafluorene (6), whereas 5 and 7 were obtained
from the acid–base reactions between the corresponding neutral ligand precursors, respectively 2-(Nphenylformimino)pyrrole (1) and 1,4-(HNC4H3-C(H)vN)2-C6H4 (2), with B(C6F5)2OEt. These complexes
were designed to evaluate the influence of the boron co-ligands on the molecular properties of the
corresponding 2-iminopyrrolyl tetrahedral boron derivatives, particularly on luminescence. Compounds
3–7 were photophysically characterised in solution and in solid state, exhibiting blue to yellowish-green
emissions and fluorescence quantum yields (ϕf) up to 0.40. The exception was complex 4, which revealed
full fluorescence quenching owing to a dynamic equilibrium involving the bidentate (tetracoordinate)
2-iminopyrrolyl boron complex and the corresponding monodentate (tricoordinate) species. DFT and
TDDFT studies were carried out, considering the effect of solvent and also of dispersion forces, in order
to elucidate the change in geometries of compounds 3–7 from the ground to the singlet excited state, to
understand the dynamic equilibrium of 4, to ascribe electronic transitions, and to rationalise the observed
luminescence and also the main trends of thermal stabilities. These complexes were applied in organic
light-emitting diodes (OLEDs), the ones based on complex 6 showing the best performances (maximum
luminance of 170 cd m−2 and electroluminescence efficiency of 0.037 cd A−1).